trans-RhCl(1-benzyl-2-imidazolyldiphenylphosphine)2 | 629597-53-1

• 英文名称: trans-RhCl(1-benzyl-2-imidazolyldiphenylphosphine)2
• CAS: 629597-53-1
• 化学式: C₄₅H₃₈ClN₄OP₂Rh
• 分子量: 851.129
• InChiKey: DWQQWZBSIABYDF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  chlorobis(ethylene)rhodium(I) dimer 、 trans-RhCl(1-benzyl-2-imidazolyldiphenylphosphine)2 生成 [(RhCl)2(μ-CO)(μ-1-benzyl-2-imidazolyldiphenylphosphine)2]
  参考文献：
  名称：

  Rhodium, iridium and gold complexes of the short-bite ligand 1-benzyl-2-imidazolyldiphenylphosphine

  摘要：

  Reactions of [{M(mu-Cl)(cod)}(2)] (M = Rh, Ir) with 1-benzyl-2-imidazolyldiphenylphosphine gave the mononuclear P-bonded compounds [MCl(cod)(Ph(2)PBzIm)]. They react with [M(cod)(acetone)(x)]BF4 to give the cationic [{M(cod)}(2)(mu-Cl)(mu-Ph(2)PBzIm)](+) complexes, while they react with silver salts to give the homometallic dinuclear complexes HT-[{M(mu-Ph(2)PBzIm)(cod)}(2)](BF4)(2) (M = Rh, Ir) containing two mutually cis bridging ligands in a HT disposition. Addition of [AuCl(tht)] to [MCl(cod)(Ph(2)PBzIm)] gave the heterometallic complexes [MCl(cod)(mu-Ph(2)PBzIm)AuCl] with the gold atom coordinated to the P-end. While the Ir-Au compound remained as such in solution. the Rh-Au complex was found to be in equilibrium with [AuCl(Ph(2)PBzIm)] and [{Rh(mu-Cl)(cod)}(2)]. Reaction of trans-[RhCl(CO)(Ph(2)PBzIm)(2)] with [{Rh(mu-Cl)(CO)(2)}(2)] gave the 'A-frame' complex [{RhCl}(2)(mu-CO)(mu-Ph(2)PBzIm)(2)] while the reaction with [PdCl2(NCMe)(2)] resulted in the formation of three isomers of the metal-metal bonded compound [(CO)Cl2Rh(mu-Ph(2)PBzIm)(2)PdCl]. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01447-0
• 作为产物：
  描述：

  (1-benzyl-2-imidazolyl)diphenylphosphine 、 di(rhodium)tetracarbonyl dichloride 以 丙酮 为溶剂， 以83%的产率得到trans-RhCl(1-benzyl-2-imidazolyldiphenylphosphine)2
  参考文献：
  名称：

  Rhodium, iridium and gold complexes of the short-bite ligand 1-benzyl-2-imidazolyldiphenylphosphine

  摘要：

  Reactions of [{M(mu-Cl)(cod)}(2)] (M = Rh, Ir) with 1-benzyl-2-imidazolyldiphenylphosphine gave the mononuclear P-bonded compounds [MCl(cod)(Ph(2)PBzIm)]. They react with [M(cod)(acetone)(x)]BF4 to give the cationic [{M(cod)}(2)(mu-Cl)(mu-Ph(2)PBzIm)](+) complexes, while they react with silver salts to give the homometallic dinuclear complexes HT-[{M(mu-Ph(2)PBzIm)(cod)}(2)](BF4)(2) (M = Rh, Ir) containing two mutually cis bridging ligands in a HT disposition. Addition of [AuCl(tht)] to [MCl(cod)(Ph(2)PBzIm)] gave the heterometallic complexes [MCl(cod)(mu-Ph(2)PBzIm)AuCl] with the gold atom coordinated to the P-end. While the Ir-Au compound remained as such in solution. the Rh-Au complex was found to be in equilibrium with [AuCl(Ph(2)PBzIm)] and [{Rh(mu-Cl)(cod)}(2)]. Reaction of trans-[RhCl(CO)(Ph(2)PBzIm)(2)] with [{Rh(mu-Cl)(CO)(2)}(2)] gave the 'A-frame' complex [{RhCl}(2)(mu-CO)(mu-Ph(2)PBzIm)(2)] while the reaction with [PdCl2(NCMe)(2)] resulted in the formation of three isomers of the metal-metal bonded compound [(CO)Cl2Rh(mu-Ph(2)PBzIm)(2)PdCl]. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01447-0