cis-RhCl(PCyPh2)[P,P-Ph(Cy)POCH2P(CH2OH)2] | 956298-49-0

• 英文名称: cis-RhCl(PCyPh2)[P,P-Ph(Cy)POCH2P(CH2OH)2]
• CAS: 956298-49-0；956222-60-9
• 化学式: C₃₃H₄₅ClO₃P₃Rh
• 分子量: 720.998
• InChiKey: FVEQLDFEEXWUFR-AGIXTPCCSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [RhCl(1,5-cyclooctadiene)(tris(hydroxymethyl)phosphine)] 、 二苯基环己基膦 以 not given 为溶剂， 生成 cis-RhCl(PCyPh2)[P,P-Ph(Cy)POCH2P(CH2OH)2] 、 cis-RhCl(PCyPh2)[P,P-Ph(Cy)POCH2P(CH2OH)2]
  参考文献：
  名称：

  Formation of a Phosphine−phosphinite Ligand in RhCl(PRR‘₂)[P,P-R‘(R)POCH₂P(CH₂OH)₂] and R‘H from cis-RhCl(PRR‘₂)₂[P(CH₂OH)₃] via P−C Bond Cleavage

  摘要：

  Reaction of RhCl(1,5-cod)(THP), where THP = P(CH2OH)(3), with several PRR'(2) phosphines (R = or not equal R') generates, concomitantly with R'H, the derivatives RhCl(PRR'(2))[PP-R'(R)POCH2P(CH2OH)(2)] in two isomeric forms. The hydrogen of the hydrocarbon co-product derives from, a THP hydroxyl group which becomes an 'alkoxy' group at the residual PRR' moiety, this resulting in the P,P-chelated R'(R)POCH2P(CH2OH)2 ligand. One of the isomers of the PPh3 system, cis-RhCl (PPh3)[P, P-P(Ph)(2)OCH2P(CH2OH)(2)], was structurally characterized (cis refers to the disposition of the P atoms with Ph substituents).

  DOI：

  10.1021/ic7012182