(Rh(phen)(nbd))ClO4 | 52445-07-5

• 英文名称: (Rh(phen)(nbd))ClO4
• CAS: 52445-07-5
• 化学式: C₁₉H₁₆N₂Rh*ClO₄
• 分子量: 474.706
• InChiKey: HYAIOQFUHCNOTP-XDWRCRRRSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (Rh(phen)(nbd))ClO4 以 乙腈 为溶剂， 生成 (Rh(phen)(nbd))
  参考文献：
  名称：

  Electrochemistry of N-heterocyclic complexes of rhodium(I) and iridium(I)

  摘要：

  DOI：

  10.1021/ic00133a031

文献信息

• Tetracyanoquinodimethanide derivatives of norbornadiene rhodium(I) fragments
  作者：Loreto Ballester、Angel Gutierrez、Reyes Jimenez、Maria Felisa Perpiñan

  DOI：10.1016/0277-5387(95)00192-u

  日期：1996.1

  The rhodium derivatives [Rh(nbd)(N-N)]X, (nbd = norbornadiene, N-N = bpy, phen, X = ClO4, BPh(4))react with anionic TCNQ(-) (7,7,8,8-tetracyanoquinodimethanido) , with total or partial substitution of the counterion but no change in the metal coordination sphere. On the contrary, rhodium derivatives with monodentate nitrogen-donor ligands, such as isoquinoline and substituted pyridines, [Rh(nbd)(N)(2)](+) (N = 2,5-Me(2)C(5)H(3)N), suffer substitution of these ligands and formation of [Rh(nbd)(TCNQ)], for which a dimeric structure with the TCNQ acting as bridges is proposed. By using the mixture TCNQ(radical anion)/TCNQ degrees the complexes with bidentate amines give rise to [Rh(nbd)(N-N)](TCNQ)(2) whose conductivity values are indicative of a higher degree of electronic delocalization in the organic donor units.