dimesityl(triphenyl-l5-arsaneyl)gold(IV) chloride | 308847-13-4

• 英文名称: dimesityl(triphenyl-l5-arsaneyl)gold(IV) chloride
• CAS: 308847-13-4
• 化学式: C₃₆H₃₇AsAuCl
• 分子量: 777.031
• InChiKey: OGZSOUNTLPOLGU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(2,4,6-三甲基苯基)汞 在 CF₃SO₃Ag 作用下， 以 乙醚 、 二氯甲烷 、 丙酮 为溶剂， 生成 dimesityl(triphenyl-l5-arsaneyl)gold(IV) chloride
  参考文献：
  名称：

  Mesityl gold(III) complexes. X-ray structure of mononuclear [Au(mes)2Cl(PPh3)] and the dimer [Au(mes)2Cl]2

  摘要：

  The reaction between PPN[AuCl4] and [Hg(mes)(2)] gives the anionic complex cis-PPN[Au(mes)(2)Cl-2] (1) and [Hg(mes)Cl] as side-product. Complex 1 is a precursor to other compounds both neutral and cationic. Removal of one chloride ligand affords the mononuclear neutral complexes cis-[Au(mes)(2)ClL] (L = PPh3 (2), P{p-tol}(3) (3), AsPh3 (4), SPPh3 (5)) by addition of a neutral ligand or, alternatively if no ligand is added, dimeric cis-[Au(mes)(2)Cl](2) (6). If both chloride groups in 1 are removed, cationic compounds can be obtained by addition of a potentially bidentate ligand affording cis-[Au(mes)(2)(L-L)]X complexes (X = ClO4, L-L = bipy (7), L-L = phen (8), L-L = dppe (9) X = SO3CF3, L-L = dppm (10)). Dithiocarbamate- or acetate salts can be added to solutions of 'Au(mes)(2)X' (obtained by removal of two chloride anions in 1) leading to the neutral compounds cis-[Au(mes),(L-L)] (L-L = S2CNR2 (R = Me (11), Et (12), Bz (13)), O2CCF3 (14)). The structures of cis-[Au(mes)(2)Cl(PPh3)] (2) and cis-[Au(mes)(2)Cl](2) (6) have been established by an X-ray diffraction study. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00306-5