| 142781-14-4

• CAS: 142781-14-4
• 化学式: C₁₁H₁₅NiO*Na
• 分子量: 244.919
• InChiKey: CQZKUPQWHXMNGD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氯化铋 以 四氢呋喃 为溶剂， 生成 [Bi(Ni(CO)(η-C5Me5))3]
  参考文献：
  名称：

  Synthetic studies on antimony and bismith complexes containing the Ni(CO)(η-C5Me5) fragment

  摘要：

  The reaction between either SbCl3 or BiCl3 and three equivalents of Na[Ni (CO)(eta-C5Me5)] affords the trinickel-element complexes [E{Ni(CO)(eta-C5Me5)}3] (E = Sb, Bi). With two equivalents of Na[Ni(CO)(eta-C5Me5)], the dinickel complexes [ECl{Ni(CO)(eta-C5Me5)}2] (E = Sb, Bi) are formed in solution, via the intermediacy of the trinickel compounds, although attempts to isolate these species led, in the case of bismuth, to the cluster compounds [Bi2Ni2(eta-C5Me5)2] and [BiNi3(eta-C5Me5)3]. All compounds were characterized by spectroscopic and analytical methods. Analogous reactions involving GaCl3 and InCl3 led only to intractable mixtures from which no pure compounds could be isolated. The reaction between Te(S2CNEt2)2 and two equivalents of Na[Ni(CO)(eta-C5Me5)] resulted not in a nickel-tellurium complex, but in the complex [Ni(S2CNEt2)(eta-C5Me5)], which was characterized by X-ray crystallography.

  DOI：

  10.1016/s0277-5387(00)83094-6
• 作为产物：
  描述：

  [Ni2(CO)2(η-C5Me5)2] 在 Na#Hg 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Synthetic studies on antimony and bismith complexes containing the Ni(CO)(η-C5Me5) fragment

  摘要：

  The reaction between either SbCl3 or BiCl3 and three equivalents of Na[Ni (CO)(eta-C5Me5)] affords the trinickel-element complexes [E{Ni(CO)(eta-C5Me5)}3] (E = Sb, Bi). With two equivalents of Na[Ni(CO)(eta-C5Me5)], the dinickel complexes [ECl{Ni(CO)(eta-C5Me5)}2] (E = Sb, Bi) are formed in solution, via the intermediacy of the trinickel compounds, although attempts to isolate these species led, in the case of bismuth, to the cluster compounds [Bi2Ni2(eta-C5Me5)2] and [BiNi3(eta-C5Me5)3]. All compounds were characterized by spectroscopic and analytical methods. Analogous reactions involving GaCl3 and InCl3 led only to intractable mixtures from which no pure compounds could be isolated. The reaction between Te(S2CNEt2)2 and two equivalents of Na[Ni(CO)(eta-C5Me5)] resulted not in a nickel-tellurium complex, but in the complex [Ni(S2CNEt2)(eta-C5Me5)], which was characterized by X-ray crystallography.

  DOI：

  10.1016/s0277-5387(00)83094-6