Platinum, tetrachlorobis(5-methyl-2H-tetrazole-κN3)-, (OC-6-11)- | 956128-25-9

• 英文名称: Platinum, tetrachlorobis(5-methyl-2H-tetrazole-κN3)-, (OC-6-11)-
• 英文别名: trans-PtCl4(5-methyl-4H-tetrazole-κN(1))2；trans-PtCl4(5-Me-4H-tz-κN(1))2
• CAS: 956128-25-9；956128-27-1
• 化学式: C₄H₈Cl₄N₈Pt
• 分子量: 505.053
• InChiKey: BYTIRVBYGHFTKA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5-甲基四氮唑 、 trans-[PtCl4(propiononitrile)2] 以 硝基甲烷 为溶剂， 以78%的产率得到Platinum, tetrachlorobis(5-methyl-2H-tetrazole-κN3)-, (OC-6-11)-
  参考文献：
  名称：

  An extended 1D network formed by complementary hydrogen bonding between Pt(IV)-complexed tetrazoles

  摘要：

  The first metal complex containing the N-1-ligated tetrazole, viz., trans- [PtCl4(5-Me-4H-tz-kappa N-1)(2)] (1), has been prepared by the reaction between trans-[PtCl4(EtCN)(2)] and 5-methyltetrazole and characterized by elemental analyses, FAB(+)-MS, IR, and H-1, C-13{H-1}, Pt-195 NMR spectroscopies and also by X-ray diffraction. In the solid state, 1 displays a novel type of complementary hydrogen-bonding between the -NH- and -N=moieties of the heterocycles from the neighbouring molecules, thus forming an extended ID network. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.10.033