bis(pyridine-2-carboxaldehyde-2'-pyridylhydrazonate)cobalt(III) hexafluorophosphate | 1346162-36-4

• 英文名称: bis(pyridine-2-carboxaldehyde-2'-pyridylhydrazonate)cobalt(III) hexafluorophosphate
• CAS: 1346162-36-4
• 化学式: C₂₂H₁₈CoN₈*F₆P
• 分子量: 598.396
• InChiKey: KMMPEZYPOJGDGV-YOMCRPSHSA-N

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 cobalt(II) nitrate hexahydrate 、 2-吡啶甲醛 2-(2-吡啶基)腙 在 NaOH 作用下， 以 甲醇 为溶剂， 生成 bis(pyridine-2-carboxaldehyde-2'-pyridylhydrazonate)cobalt(III) hexafluorophosphate
  参考文献：
  名称：

  Spectroscopy, electrochemistry, and nucleophilicity of nickel and cobalt complexes of 2′-pyridine carboxaldehyde 2′-pyridyl hydrazone (papyH)

  摘要：

  Nickel and cobalt complexes of pyridine-2-carboxaldehyde-2'-pyridylhydrazone (papyH) and N-methyl(pyridine-2-carboxaldehyde-2'-pyridyl-hydrazone) (papyMe) have been fully characterized through electrochemistry, titration, and alkylation with methyl iodide and compared with existing data on zinc and iron complexes. Both rate constants for alkylation and ligand pKa depend on the coordinated metal and can be understood based on the influence of d electrons on the ligand molecular orbitals. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.08.037