| 886848-08-4

• CAS: 886848-08-4
• 化学式: C₁₄H₉ClFeO₃SSe
• 分子量: 427.55
• InChiKey: MIUCXSXXSQWVIJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 四氢呋喃 为溶剂， 以90%的产率得到[CpFe(CO)(κ-2 Se,S-SeC(S)O-4-C6H4Cl]
  参考文献：
  名称：

  Selenothiocarbonate complexes of iron: Structure of CpFe(CO)2SeC(S)O-4-C6H4Cl

  摘要：

  Stable complexes of general formula CpFe(CO)(2)SeC(S)OR, where R = Ph (1a), 4-C6H4Cl (1b), 4-C6H4F (1c), C6F5 (1d), 4-C6H4CH3 (1e), were prepared by the reaction of (mu-Se)[CpFe(CO)(2)](2) with ROC(S)Cl at room temperature. When a THF solution of 1 was photolyzed the chelate complexes CpFe(CO)(kappa(2)Se,S-SeC(S)OR) (2) were obtained in good yields. All of these complexes have been characterized by elemental analyses, IR and H-1 NMR spectroscopy, The structure of CpFe(CO)(2)SeC(S)O-4-C6H4Cl (1b) is reported. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.09.024
• 作为产物：
  描述：

  4-氯苯基氯硫代甲酸酯 、 (μ-Se)[CpFe(CO)2]2 以 乙醚 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Selenothiocarbonate complexes of iron: Structure of CpFe(CO)2SeC(S)O-4-C6H4Cl

  摘要：

  Stable complexes of general formula CpFe(CO)(2)SeC(S)OR, where R = Ph (1a), 4-C6H4Cl (1b), 4-C6H4F (1c), C6F5 (1d), 4-C6H4CH3 (1e), were prepared by the reaction of (mu-Se)[CpFe(CO)(2)](2) with ROC(S)Cl at room temperature. When a THF solution of 1 was photolyzed the chelate complexes CpFe(CO)(kappa(2)Se,S-SeC(S)OR) (2) were obtained in good yields. All of these complexes have been characterized by elemental analyses, IR and H-1 NMR spectroscopy, The structure of CpFe(CO)(2)SeC(S)O-4-C6H4Cl (1b) is reported. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.09.024

文献信息

• Photochemical substitution of a single CO ligand of CpFe(CO)2SeC(Y)Y′Ar [(Y)Y′ = (O)O, (S)O and (S)S] by EPh3 (E = P, As, Sb)
  作者：Mohammad El-khateeb、Mohammad Harb、Alaa Mansour、Sammer Yousuf

  DOI：10.1016/j.ica.2018.09.063

  日期：2019.2

  Abstract New iron complexes containing selenocarbonato, selenothiocarbonato and selenodithiocarbonato ligands in addition to CO/EPh3 mixed ligands are synthesized and characterized. CpFe(CO)(EPh3)SeC(Y)Y′Ar [(Y)Y′ = (O)O; Ar = C6H5 (1). (Y)Y′ = (S)O; Ar = 4-C6H4Cl (2). (Y)Y′ = (S)S; Ar = C6H5 (3). E = P (a), As (b), Sb (c)] are accessible from the reactions of CpFe(CO)2SeC(Y)Y′Ar with EPh3 under photolytic

  摘要合成并表征了新的铁配合物，该配合物还含有硒代碳原子，硒代硫代碳原子和硒代二硫代碳原子的配体以及CO / EPh3混合配体。CpFe（CO）（EPh3）SeC（Y）Y'Ar [（Y）Y'=（O）O; Ar ＝ C 6 H 5（1）。（Y）Y'=（S）O; Ar ＝ 4-C 6 H 4 Cl（2）。（Y）Y'=（S）S; Ar ＝ C 6 H 5（3）。E = P（a），As（b），Sb（c）]可在光解条件下从CpFe（CO）2SeC（Y）Y'Ar与EPh3的反应获得。新的配合物已通过各种光谱方法（UV-Vis，IR，1H-，31P-，13C-，77Se-NMR）和元素分析进行​​了表征。单晶X射线晶体结构分析进一步支持了CpFe（CO）（AsPh3）SeC（O）OC6H5（1b）的确定结构。