bis[(O-Sn)-ethanol]-bis-(3,5-di-tert-butyl-2-oxo-phenyl)oxamido-bis-(chlorophenyltin) | 326475-18-7

• 英文名称: bis[(O-Sn)-ethanol]-bis-(3,5-di-tert-butyl-2-oxo-phenyl)oxamido-bis-(chlorophenyltin)
• CAS: 326475-18-7
• 化学式: C₄₆H₆₂Cl₂N₂O₆Sn₂
• 分子量: 1047.33
• InChiKey: NTAUJWZXUVNIAC-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis-(3,5-di-tert-butyl-2-phenol)-oxamide 、 苯基三氯化锡 在 triethylamine 作用下， 以 乙醇 为溶剂， 以72%的产率得到bis[(O-Sn)-ethanol]-bis-(3,5-di-tert-butyl-2-oxo-phenyl)oxamido-bis-(chlorophenyltin)
  参考文献：
  名称：

  New hexacyclic binuclear tin complexes derived from bis-(3,5-di-tert-butyl-2-phenol)oxamide

  摘要：

  The syntheses of bis-(3,5-di-tert-butyl-2-phenol)oxamide (2a) and four new hexacyclic bimetallic tin compounds derivatives are reported: bis-(3,5-di-tert-butyl-2-oxo-phenyl)-oxamido-bis(dibutyltin) (3), bis-(3,5-di-tert-butyl-2-oxo-phenyl)-oxamido-bis(diphenyltin) (4), bis(triethylammonium) bis-(3,5-di-tert-butyl-2-oxo-phenyl)-oxamido-bis-(dichlorobutyl-stannate) (5), and bis[(O-Sn) ethanol]-bis-(3, 5-di-tert-butyl-2-oxo-phenyl)-oxamido-bis-(chlorophenyltin) (6). All tin compounds show a planar ligand skeleton in which each tin atom is linked to the phenoxy group, to the anilinic nitrogen atom and to the oxygen of the oxamide group. Compounds 3 and 4 have two pentacoordinated diorganyl tin atoms with a distorted bpt geometry, whereas 5 contains a dianionic structure with two hexacoordinated tin atoms bonded to a n-butyl group and to two chlorine atoms and two triethyl ammonium as counterions. Compound 6 has two hexacoordinated tin atoms, each atom is bonded, in addition to the ligand, to one phenyl and one chlorine and coordinated to an ethanol molecule. Characterization of the compounds was made through usual analytical and spectroscopic methods. Structures of 4,6-di-tert-butyl-1-phenol-2-amine 1, the oxamide 2a and the four tin compounds 3-6 were established by the X-ray diffraction analyses. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00689-6