cyclopentadienyldicarbonyliron(SCOOCH2CH(CH3)2) | 671205-03-1

• 英文名称: cyclopentadienyldicarbonyliron(SCOOCH2CH(CH3)2)
• CAS: 671205-03-1
• 化学式: C₁₂H₁₄FeO₄S
• 分子量: 310.154
• InChiKey: CRSVZLJFHSAVMA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cyclopentadienyldicarbonyliron(μ-S)(x) 、 氯甲酸异丁酯 以 乙醚 为溶剂， 以65%的产率得到cyclopentadienyldicarbonyliron(SCOOCH2CH(CH3)2)
  参考文献：
  名称：

  Half sandwich iron S-bonded mono-thiocarbonate complexes: structure of CpFe(CO)2SCO2Et

  摘要：

  The synthesis and characterization of mononuclear iron complexes containing mono-thiocarbonate ligands are described. The new compounds of general formula CpFe(CO)(2)SCO2R [R = Et (1), iso-Bu (2), Ph (3), 4-C6H4NO2 (4), Me (5)] were prepared by reacting the iron sulfides (mu-S-x)[CpFe(CO)(2)](2) (x = 2, 3) with the corresponding chloroformates (ROCOCI). These new complexes have been characterized by elemental analyses and spectroscopic methods. The crystal structure of CpFe(CO)(2)SCO2Et, 1, has been determined by single crystal X-ray diffraction analysis. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00465-0