trans-[FeH(ethylisocyanide)(dppe)2][BF4] | 404844-16-2

• 英文名称: trans-[FeH(ethylisocyanide)(dppe)2][BF4]
• CAS: 404844-16-2
• 化学式: BF₄*C₅₅H₅₄FeNP₄
• 分子量: 995.587
• InChiKey: FMVAFTMVAAYKKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trans-[FeH(CN)(PPh2(CH2)2PPh2)2] 、 triethyloxonium fluoroborate 以 四氢呋喃 为溶剂， 生成 trans-[FeH(ethylisocyanide)(dppe)2][BF4]
  参考文献：
  名称：

  Cyanide as a versatile Lewis base ligand at a dinitrogen-binding iron(II) centre: mono- and heteronuclear adducts

  摘要：

  The ligated cyanide in trans-[FeH(CN)(dppe)(2)] is activated towards aroylation, alkylation and addition of various transition metal Lewis acids, in particular [WCl4(PPh3)(2)], [ReOCl3(PPh3)(2)], [PdCl2(PPh3)(2)] and [PtCl(Ph)(PPh3)(2)], to give, in the former case, mononuclear isocyanide complexes and, in the latter case, heteronuclear adducts with bridging cyanide. Their syntheses and spectroscopic characterisation are presented, as well as results of the X-ray diffraction analyses of a trinuclear complex with the {Fe-Cequivalent toN-W-Nequivalent toC-Fe} unit and of the parent cyano trans-[FeH(CN)(dppe)(2)] complex. The cyanide bridge allows the electronic communication between the metal centres as indicated by a cyclic voltammetric study. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00249-4