| 1429492-32-9

• CAS: 1429492-32-9
• 化学式: C₂₆H₂₉Cl₂N₂P₂Ru
• 分子量: 603.453
• InChiKey: XCBHMPICWBEZOT-NMGGKPDLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 2,3,4,5,6,7,8,9-octahydro-1,9-diphenyl-1H-5,1,9-benzazadiphosphacyclo undecine 、 乙腈 反应 12.0h， 以76%的产率得到
  参考文献：
  名称：

  Coordination chemistry and catalytic activity of ruthenium(II) complexes containing a phospha-macrocyclic ligand

  摘要：

  Substitution of [RuCl2(CO)(3)(THF)], [RuCl2(dmso)(4)] and [RuCl2(PPh3)(3)] with a macrocyclic ligand, 2,3,4,5,6, 7,8,9-octahydro-1,9-diphenyl-1H-5,1,9-benzazadiphosphacyclo undecine (11-P2NH), provided [Ru(11-P2NH)Cl-2(CO)] (3), [Ru(11-P2NH)Cl-2(dmso)] (4) and [Ru(11-P2NH)Cl-2(CH3CN)] (5), respectively. These complexes were characterized by elemental analyses as well as NMR spectroscopy. The structure of 3 was further confirmed by X-ray diffraction analysis. The octahedral geometry around the ruthenium center is in agreement with the Werner's "coordination" bonding concepts. The chelate rings of the macrocycle toward Ru(II) center adopting into chair conformations were revealed. Furthermore, these ruthenium complexes were found to be active for N-alkylation of dibenzylamine with alcohols. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.079