(2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octadionato)silver vinyltriethylsilane dimer | 177279-30-0

• 英文名称: (2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octadionato)silver vinyltriethylsilane dimer
• CAS: 177279-30-0
• 化学式: C₃₆H₅₆Ag₂F₁₄O₄Si₂
• 分子量: 1090.72
• InChiKey: MRIOKDTXHSZWPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三乙基乙烯基硅烷 、 2,2-二甲基-6,6,7,7,8,8,8-七氟-3,5-辛二酮 、 silver(l) oxide 以 乙醚 为溶剂， 以88%的产率得到(2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octadionato)silver vinyltriethylsilane dimer
  参考文献：
  名称：

  Synthesis and Characterization of (β-Diketonato)silver Vinyltriethylsilane Compounds and Their Application to CVD of Silver Thin Films. Crystal Structure of the (2,2-Dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedionato)silver Vinyltriethylsilane Dimer

  摘要：

  New silver complexes of alkenes of empirical formula (beta-diketonato)Ag(VTES), where beta-diketonato = 1,1,1,5,5,5-hexafluoro-2,4-pentanedionato (hfac), (1),1,1,1-trifluoro-2,4-pentanedionato (hfac) (2), and 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedionato (fod) (3) and VTES = vinyltriethylsilane, were prepared from reactions of Ag2O with beta-diketones in the presence of VTES. All compounds were characterized by elemental analyses and H-1, C-13, and F-19 NMR and IR spectra. The crystal structure of compound 3 determined by X-ray diffraction analysis showed a dimeric silver species with coordination of the C=C double bond of VTES, two oxygen atoms of a chelating fod ligand, and the methine C atom of another fod in the solid state. Hot-wall chemical vapor deposition experiments revealed that compound 1 is suitable as a precursor to deposit pure silver films in the temperature range 160-280 degrees C.

  DOI：

  10.1021/om960013e