[(p-cymene)RuCl2]2(1,2-di(4-pyridyl)ethylene) | 1391359-22-0

• 英文名称: [(p-cymene)RuCl2]2(1,2-di(4-pyridyl)ethylene)
• CAS: 1391359-22-0
• 化学式: C₃₂H₃₈Cl₄N₂Ru₂
• 分子量: 794.619
• InChiKey: HWBFOYPPCPGFEM-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 1,2-双吡啶基乙烯 以 二氯甲烷 为溶剂， 以85%的产率得到[(p-cymene)RuCl2]2(1,2-di(4-pyridyl)ethylene)
  参考文献：
  名称：

  Dinuclear arene ruthenium dichloro complexes designed for host–guest propensity

  摘要：

  The synthesis and the crystal structures of several wheel-and-axle metal-organic (waamo) complexes are studied. The design of such systems is basically constituted by the binding between two Ru(II)(p-cymene) Cl-2 units (wheels) and an organic spacer (axle), bearing pyridinic and/or cyano functions. Particular attention is given to the solid-state organization of the waamo complexes and to their propensity to create acceptors sites for guest species The inverted piano-stool motif, a characteristic synthon of half-sandwich ruthenium units, is always observed here, generating well defined layers of host molecules. Both polycatenated and host-guest systems were generated in order to achieve a compact packing. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.03.020