[{(HC[(CMe)N(2,4,6-Me₃C₆H₂)]₂)Al(SeH)}₂(μ-Se)] | 1426396-13-5

• 英文名称: [{(HC[(CMe)N(2,4,6-Me₃C₆H₂)]₂)Al(SeH)}₂(μ-Se)]
• CAS: 1426396-13-5
• 化学式: C₄₆H₆₀Al₂N₄Se₃
• 分子量: 959.852
• InChiKey: IJRUBRLWSCKJHZ-OZZGTHGUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  环八硒 、 (HC[(CMe)N(2,4,6-Me3C6H2)]2)AlH2 以 甲苯 为溶剂， 反应 12.0h， 以67%的产率得到[{(HC[(CMe)N(2,4,6-Me₃C₆H₂)]₂)Al(SeH)}₂(μ-Se)]
  参考文献：
  名称：

  Preparation of Telluro- and Selenoalumoxanes under Mild Conditions

  摘要：

  Syntheses of the heavy chalcogen-containing alumoxanes [(LAl)-L-Me(SeH)](2)(mu-O) (4) and ((LAl)-L-Me)(2)(mu-Te)(mu-O) (7) were accomplished by the reaction of ((LAlH)-L-Me)(2)(mu-O) (2; L-Me = HC[(CMe)N(2,4,6-Me3C6H2)](2)(-)) with either red selenium or metallic tellurium. The aluminum hydrogenselenide [(LAl)-L-Me(SeH)](2)(mu-Se) (3) was also prepared from the reaction of red selenium and (LAlH2)-L-Me (1). All compounds were characterized by spectroscopic methods and X-ray diffraction studies. Density functional theory calculations were performed on 4 and 7.

  DOI：

  10.1021/ic302588f