[(5,6-dimethyl-1,10-phenanthroline)Re(CO)3(NC5H4-4-COOH)]ClO4 | 264262-40-0

• 英文名称: [(5,6-dimethyl-1,10-phenanthroline)Re(CO)3(NC5H4-4-COOH)]ClO4
• CAS: 264262-40-0
• 化学式: C₂₃H₁₇N₃O₅Re*ClO₄
• 分子量: 701.063
• InChiKey: YZQXKGZTBVUSAH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  N-羟基丁二酰亚胺 、 1,12-二氨基十二烷 、 [(5,6-dimethyl-1,10-phenanthroline)Re(CO)3(NC5H4-4-COOH)]ClO4 在 dicyclohexylcarboxydiimide 作用下， 以 二氯甲烷 为溶剂， 生成 [(5,6-dimethyl-1,10-phenanthroline)Re(CO)3(NC5H4-4-CONH(CH2)12NHCOCH3)]ClO4
  参考文献：
  名称：

  Effects of diffusion on energy transfer in solution using a microsecond decay time rhenium metal–ligand complex as the donor

  摘要：

  We used resonance energy transfer and frequency-domain fluorometry to measure slow donor to acceptor diffusion in viscous media. The frequency-domain RET data were analyzed using a new numerical algorithm for predicting the donor intensity decay in the presence of diffusion occurring within the donor decay time. By the use of a rhenium metal-ligand complex as a microsecond decay time donor we were able to measure mutual donor-to-acceptor diffusion coefficients as low as 2 X 10(-8) cm(2)/s. The availability of microsecond decay time luminophores and appropriate theory suggests the use of diffusion-enhanced energy transfer for measurement of diffusive processes and structural dynamics in biological systems. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(00)00071-3