[RuH(CO)(triphenylphosphine)2(1,10-phenanthroline)]Cl*H2O*acetone | 1204739-82-1

• 英文名称: [RuH(CO)(triphenylphosphine)2(1,10-phenanthroline)]Cl*H2O*acetone
• 英文别名: [RuH(CO)(PPh3)2(1,10-phen)]Cl*H2O*(CH3)2CO
• CAS: 1204739-82-1
• 化学式: C₃H₆O*C₄₉H₃₉N₂OP₂Ru*Cl*H₂O
• 分子量: 946.427
• InChiKey: LYBGEWLOQKUBPE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  丙酮 、 [RuHCl(CO)(PPh₃)₃] 、 邻菲罗啉 以 丙酮 为溶剂， 以65%的产率得到[RuH(CO)(triphenylphosphine)2(1,10-phenanthroline)]Cl*H2O*acetone
  参考文献：
  名称：

  Synthesis, spectroscopic and structural characterizations of two new complexes of ruthenium with 2-(hydroxymethyl)benzimidazole and 1,10-phenanthroline ligands

  摘要：

  The complexes [RuCl(CO)(PPh(3))(2)(HBIm)] and [RuH(Co)(PPh(3))(2)(1,10-phen)]Cl center dot H(2)O center dot(CH(3))(2)O have been prepared and studied by IR and UV-Vis spectroscopy, and X-ray crystallography. The complexes were prepared in the reactions of [RuHCl(CO)(PPh(3))(3)] with 2-(hydroxymethyl)benzimidazole or 1,10-phenanthroline two hydrate in acetone. The electronic spectra of the obtained compounds have been calculated using the TDDFT method. The luminescence properties of these complexes were examined. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.08.035