([methylpalladium(1-diisopropylphosphino-2-di(t-butyl)phosphinylbenzene)(2,6-lutidine)][hexafluoroantimonate]) | 1375327-34-6

• 英文名称: ([methylpalladium(1-diisopropylphosphino-2-di(t-butyl)phosphinylbenzene)(2,6-lutidine)][hexafluoroantimonate])
• 英文别名: [PdMe(iPr2PC6H4POtBu2)(2,6-lutidine)]SbF6
• CAS: 1375327-34-6
• 化学式: C₂₈H₄₈NOP₂Pd*F₆Sb
• 分子量: 818.803
• InChiKey: NZIDHIICKVQIOD-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ([methylpalladium(1-diisopropylphosphino-2-di(t-butyl)phosphinylbenzene)(2,6-lutidine)][hexafluoroantimonate]) 、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 二氯甲烷 为溶剂， 反应 0.33h， 以95%的产率得到[methylpalladium(1-diisopropylphosphino-2-di(t-butyl)phosphinylbenzene)(2,6-lutidine)][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]
  参考文献：
  名称：

  CATALYST FOR SYNTHESIZING POLYOLEFINS

  摘要：

  公开号：

  EP2848623B1
• 作为产物：
  描述：

  2,6-二甲基吡啶 、 silver hexafluoroantimonate 、 chloromethyl(1,5-cyclooctadiene)palladium(II) 、 iPr2C6H4POtBu2 以 二氯甲烷 为溶剂， 生成 ([methylpalladium(1-diisopropylphosphino-2-di(t-butyl)phosphinylbenzene)(2,6-lutidine)][hexafluoroantimonate])
  参考文献：
  名称：

  Synthesis of Functional Polyolefins Using Cationic Bisphosphine Monoxide–Palladium Complexes

  摘要：

  The copolymerization of ethylene with polar vinyl monomers, such as vinyl acetate, acrylonitrile, vinyl ethers, and allyl monomers, was accomplished using cationic palladium complexes ligated by a bisphosphine monoxide (BPMO). The copolymers formed by these catalysts have highly linear microstructures and a random distribution of polar functional groups throughout the polymer chain. Our data demonstrate that cationic palladium complexes can exhibit good activity for polymerizations of polar monomers, in contrast to cationic a-diimine palladium complexes (Brookhart-type) that are not applicable to industrially relevant polar monomers beyond acrylates. Additionally, the studies reported here point out that phosphine-sulfonate ligated palladium complexes are no longer the singular family of catalysts that can promote the reaction of ethylene with many polar vinyl monomers to form linear functional polyolefins.

  DOI：

  10.1021/ja303507t