(η5-C5H5)Fe(CO)2(η2-1,3-butadiene) hexafluorophosphate | 36119-40-1

• 英文名称: (η5-C5H5)Fe(CO)2(η2-1,3-butadiene) hexafluorophosphate
• CAS: 36119-40-1
• 化学式: C₁₁H₁₁FeO₂*F₆P
• 分子量: 376.018
• InChiKey: YEXDIYDIDVUCEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η5-C5H5)Fe(CO)2(η2-1,3-butadiene) hexafluorophosphate 、 三苯基膦 以 丙酮 为溶剂， 以92%的产率得到(η5-C5H5)Fe(CO)2(triphenylphosphino) hexafluorophosphate
  参考文献：
  名称：

  The synthesis, characterization and some reactions of cationic η2-(α,ω-diene) complexes of iron

  摘要：

  The cationic iron eta (2)-(alpha,omega -diene) complexes of the type, [(eta (5)-C5H5)Fe(CO)(2){eta (2)-(alpha,omega -diene)}]PF6, (diene = 1,3-butadiene; 1,4-pentadiene; 1,5-hexadiene; and 1,7-octadiene) were prepared by the reaction of eta (1)-alkenyl compounds of the type [(eta (5)-C5H5)Fe(CO)(2)(eta (1)-alkenyl)] with the so-called trityl salt, (Ph3CPF6). The reactions of the eta (2)-diene complexes with a number of nucleophiles give a range of products resulting from nucleophillic addition to the coordinated diene and/or displacement of the diene. The reaction with triethylamine results in deprotonation leading to the formation of [(eta (5)-C5H5)Fe(CO)(2)(eta (1)-allyl)] complexes. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00649-5
• 作为产物：
  描述：

  (η5-C5H5)Fe(CO)2(η1-butenyl) 、 tritylium hexafluorophosphate 以 二氯甲烷 为溶剂， 以49%的产率得到(η5-C5H5)Fe(CO)2(η2-1,3-butadiene) hexafluorophosphate
  参考文献：
  名称：

  The synthesis, characterization and some reactions of cationic η2-(α,ω-diene) complexes of iron

  摘要：

  The cationic iron eta (2)-(alpha,omega -diene) complexes of the type, [(eta (5)-C5H5)Fe(CO)(2){eta (2)-(alpha,omega -diene)}]PF6, (diene = 1,3-butadiene; 1,4-pentadiene; 1,5-hexadiene; and 1,7-octadiene) were prepared by the reaction of eta (1)-alkenyl compounds of the type [(eta (5)-C5H5)Fe(CO)(2)(eta (1)-alkenyl)] with the so-called trityl salt, (Ph3CPF6). The reactions of the eta (2)-diene complexes with a number of nucleophiles give a range of products resulting from nucleophillic addition to the coordinated diene and/or displacement of the diene. The reaction with triethylamine results in deprotonation leading to the formation of [(eta (5)-C5H5)Fe(CO)(2)(eta (1)-allyl)] complexes. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00649-5