Pt(1,2-phenylenediamine)(benzo[h]quinoline)PF6 | 1296306-79-0

• 英文名称: Pt(1,2-phenylenediamine)(benzo[h]quinoline)PF6
• CAS: 1296306-79-0
• 化学式: C₁₉H₁₆N₃Pt*F₆P
• 分子量: 626.4
• InChiKey: JFVRDASDZWBSEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 tetra-n-butylammonium dichloro[2-(2-quinolyl)phenyl-3-ido]platinum 、 邻苯二胺 以 乙二醇甲醚 、 水 、 二甲基亚砜 为溶剂， 以72%的产率得到Pt(1,2-phenylenediamine)(benzo[h]quinoline)PF6
  参考文献：
  名称：

  Cyclometalated platinum(II) complexes bearing o-phenylenediamine derivatives: Synthesis and electrochemical behavior

  摘要：

  New cyclometalated Pt(II) complexes bearing 1,2-phenylenediamine (pda) derivatives were synthesized and their chemical and electrochemical properties were investigated. Two Pt complexes, [Pt(bzqn) (pda)] (PF6) (bzqn benzo[h] quinoline, [1](PF6): pda 1,2-phenylenediamine, [2](PF6): pda 4,5-dimethyl-1,2- phenylenediamine), were synthesized by the reaction of (Bu4N)[PtCl2(bzqn)] with corresponding pda derivatives. The Pt-pda complexes were converted to Pt-bda (bda = 1,2-benzenediamide) complexes by treatment of 2 mol equiv of 1,8-diazabicyclo[5.4.0] undec-7-ene (DBU), and they showed two-step reversible redox couples in cyclic voltammetry. The cyclometalated ligand gave a strong electronic effect to the bda ligand to take place the negative shift of the bda-based redox potentials. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.12.003