[(η(5)-C5Me5)Ru(η(2)-CH2=CH2)]2(μ-H)(μ-N=CHCH3) | 176903-05-2

• 英文名称: [(η(5)-C5Me5)Ru(η(2)-CH2=CH2)]2(μ-H)(μ-N=CHCH3)
• CAS: 176903-05-2
• 化学式: C₂₆H₄₃NRu₂
• 分子量: 571.774
• InChiKey: FMDFDDLFFBZNCN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙烯 、 [(η(5)-C5Me5)Ru]2(CH3CN)2(μ-H)(μ-N=CHCH3) 以 四氢呋喃 为溶剂， 以97%的产率得到[(η(5)-C5Me5)Ru(η(2)-CH2=CH2)]2(μ-H)(μ-N=CHCH3)
  参考文献：
  名称：

  Novel Dinuclear (μ-Hydrido)(μ-alkylideneamido)ruthenium Complexes, [(η⁵-C₅Me₅)Ru]₂(μ-L)(μ-H)(μ-NCHR) (R = Me, Et; L = MeCN, Arene), as Precursors of Active Species for Bimetallic Activation. Dehydrogenative Coupling of Ethylene in a Dinuclear Ruthenium Complex

  摘要：

  The dinuclear ruthenium tetrahydride [(eta(5)-C(5)Me(5))Ru(mu-H)(2)](2) reacts with acetonitrile or propionitrile in the presence of an arene such as toluene or naphthalene to generate the (mu-hydrido)(mu-alkylideneamido)-ruthenium complex (Cp'Ru)(2)(mu-L)(mu-H)(mu-N=CHR) (L=(arene); Cp'=eta(5)-C(5)Me(5)). The reaction of the (mu-alkylideneamido)ruthenium complex with ethylene gives the bis(ethylene)ruthenium complex [Cp'Ru(eta(2)-CH2=CH2)](2)-(mu-H)mu-N=CHCH3), which undergoes dehydrogenative coupling of the ethylene ligand to yield the mu-eta(2):eta(2)-s-cis-butadiene complex (Cp'Ru)(2)(mu-eta(2):eta(2)-CH2=CHCH=CH2)-(mu-H)(mu-N=CHCH3).

  DOI：

  10.1021/om950942q