[Ni(allyl)(((CH3)2CH)2C6H3NCH(CHCHCH3)CNC6H3(CH(CH3)2)2)] | 1337992-59-2

• 英文名称: [Ni(allyl)(((CH3)2CH)2C6H3NCH(CHCHCH3)CNC6H3(CH(CH3)2)2)]
• 英文别名: [nickel(I)(allyl)(bis(2,6-diisopropylphenyl)(NCHC(CHCHCH3)N)]
• CAS: 1337992-59-2
• 化学式: C₃₂H₄₅N₂Ni
• 分子量: 516.413
• InChiKey: WVIGLAZCUAMUTN-JOOUIODYSA-N

反应信息

• 作为产物：
  描述：

  [nickel(II)(allyl)(bis(2,6-diisopropylphenyl)(NCH2C(CHCHCH3)N)] 以 四氢呋喃 为溶剂， 反应 12.0h， 生成 [Ni(allyl)(((CH3)2CH)2C6H3NCH(CHCHCH3)CNC6H3(CH(CH3)2)2)]
  参考文献：
  名称：

  顺磁性Ni（I）和Ni（III）配合物在不饱和烃催化反应中的作用

  摘要：

  通过对通过系统研究Ni（I）配合物形成条件而收集的实验数据进行分析，结果表明，当系统同时包含被烯烃或有机元素配体稳定的Ni（0）和Ni（II）配合物时，无论是阳离子性还是电子中性，配合物经历相称形成Ni（I）配合物。以单个的Ni（II）配合物为例，表明氢化物和有机金属Ni（II）配合物的自发分解产生Ni（I）配合物。Ni（I）和Ni（III）配合物参与烯烃和乙炔反应的催化循环。

  DOI：

  10.1134/s0023158412040106

文献信息

• Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 – (2,6-diisopropylphenyl)diazabutadiene system
  作者：Peter B. Kraikivskii、Vitaly V. Saraev、Victoria V. Bocharova、Galina V. Romanenko、Stanislav K. Petrovskii、Dmitrii A. Matveev

  DOI：10.1016/j.jorganchem.2011.07.023

  日期：2011.11

  It has been shown that the reaction of Ni(allyl)(2) with (2,6-diisopropylphenyl)diazabutadiene gives the imino-amide Ni complex (1). The imino-amide moiety of this complex undergoes some complicated rearrangements resulting in spontaneous formation of a paramagnetic pi-allyl Ni(I) complex. Nickel complexes formed in the system have been studied with ESR, FTIR, 2D NMR, and mass spectrometry. The structure of complex 1 was studied with X-ray diffraction. (C) 2011 Elsevier B. V. All rights reserved.
• Nickel(I) complex as the final product of the sequence of spontaneous transformations in the system Ni(allyl)2-(2,6-diisopropylphenyl)diazabutadiene
  作者：P. B. Kraikivskii、V. V. Saraev、V. V. Bocharova、G. V. Romanenko、D. A. Matveev、S. K. Petrovskii、A. S. Kuzakov

  DOI：10.1134/s1070328412050053

  日期：2012.6

  A reaction of Ni(Allyl)(2) with bis(2,6-diisopropylphenyl)diazabutadiene gave an imino amide allyl nickel(II) complex (I). Complicated rearrangements of the imino amide ligand in the coordination sphere of complex I spontaneously yielded a paramagnetic Ni(I) pi-allyl complex as a final reaction product. The nickel complexes produced in this system were studied by EPR, IR, and 2D NMR spectroscopy and mass spectrometry. Structure I was examined by X-ray diffraction.