Ru(1,5-cyclooctadiene)bis(N,N-dimethyldithiocarbamato) | 52314-49-5

• 英文名称: Ru(1,5-cyclooctadiene)bis(N,N-dimethyldithiocarbamato)
• CAS: 52314-49-5
• 化学式: C₁₄H₂₄N₂RuS₄
• 分子量: 449.692
• InChiKey: RWZNIYCUOOEIDB-PHFPKPIQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro(1,5-cyclooctadiene)ruthenium(II) 、 sodium dimethyldithiocarbamate 以 not given 为溶剂， 生成 Ru(1,5-cyclooctadiene)bis(N,N-dimethyldithiocarbamato)
  参考文献：
  名称：

  Dynamic stereochemistry of bis-β-diketonato-1,5-cyclooctadiene ruthenium(II) complexes

  摘要：

  Tris(chelate)2(diene)ruthenium(II) complexes have been synthesized. All three possible diastereoisomers of Ru(bzac)2(cod) (where cod = 1,5-cyclooctadiene and bzac = benzoylacetonato) have been isolated and diastereoisomerization processes were observed at elevated temperature. The energy barriers were found to be in the range of 35-36 kcal/mol. The DNMR behaviour of Ru(S2CNMe2)2(cod) and Ru(S2PMe2)2(L) complexes is also discussed. We synthesized a new Ru(N-isopropylsalicylaldiminato)2(cod) tris-chelate which was found to clathrate some solvents.

  DOI：

  10.1016/s0020-1693(00)87941-4