(Hg(SeC6H5)(μ-SeC6H5)(μ-Cl)Ag(PC6H5)3)2)*dmf | 1356918-54-1

• 英文名称: (Hg(SeC6H5)(μ-SeC6H5)(μ-Cl)Ag(PC6H5)3)2)*dmf
• CAS: 1356918-54-1
• 化学式: C₃H₇NO*C₄₈H₄₀AgClHgP₂Se₂
• 分子量: 1253.72
• InChiKey: YJIKEGXPZRBVRC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (AgCl(PPh3)2) 、 di(phenylselenenyl)mercury 、 N,N-二甲基甲酰胺 以 二氯甲烷 、 乙腈 为溶剂， 以58%的产率得到(Hg(SeC6H5)(μ-SeC6H5)(μ-Cl)Ag(PC6H5)3)2)*dmf
  参考文献：
  名称：

  Construction of heterobimetallic Cd(Hg)/Cu(Ag)/S(Se) complexes from homoleptic [Hg(EPh)2] molecules and [Cd(EPh)4]2− anions (E=S, Se)

  摘要：

  Treatment of [Hg(EPh)(2)] with 2 equivalents of [Cu(PPh3)(2)Cl] gave the trinuclear Hg/Cu/S(Se) complexes [Hg(mu-EPh)(2)(CuCl(PPh3)(2))] (E = S 1, Se 2) in which the two copper centers are ligated by the [PhE](-) ligands of the [Hg(EPh)(2)]. A similar reaction of [Hg(EPh)(2)] with [Ag(PPh3)(2)Cl] gave rise to isolation of the dinuclear compounds [Hg(SePh)(mu-SePh)(mu-Cl)Ag(PPh3)(2)] (E = S 3, Se 4) in which the coordination geometry of the mercury atom is a slightly distorted T-shape. Reactions of the homoleptic tetrahedral species [Cd(EPh)(4)](2-) with 2 equivalents of [Cu(PPh3)(2)NO3] afforded the neutral linear trinuclear complexes [Cd(mu-EPh)(4)[Cu(PPh3)(2))(2)](E = S 5, Se 6) in which two [Cu(PPh3)(2)](+) fragments bind with the opposite edges of a tetrahedral [Cd(EPh)(4)](2-) moiety via the sulfur or selenium atoms of the PhE- ligands. A similar reaction of [Me4N](2)[Cd(SPh)(4)] with 2 equivalents of [Ag(PPh3)(2)NO3] gave an analogous complex [Cd(mu-SPh)(4){Ag(PPh3)(2)}(2)] (7), whereas the reaction of [Me4N](2)[Cd(EPh)(4)] with an equivalent amount of [Ag(PPh3)(2)NO3] under similar conditions afforded the neutral heptanuclear complexes [Cd-3(mu-EPh)(6) (mu(3)-EPh)(4)(AgPPh3)(4)] (E = S 8, Se 9) which comprise three [(AgPPh3)](+) fragments side-ligated and one [(AgPPh3)](+) fragment side-capped with the trinuclear cadmium-thio(seleno)phenolate [Cd-3(mu-EPh)(9) (mu(3)-EPh)](4-) moieties via the sulfur atoms of thiophenolates in 8 and the selenium atoms of selenophenolates in 9. The nonlinear optical properties of two neutral heptanuclear complexes 8 and 9 have been examined by z-scan techniques with 7-ns pulses at 532 nm. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.046