[(dihexyl sulfoxide)IrCl5][dihexyl sulfoxide(+1H)] | 924266-33-1

• 英文名称: [(dihexyl sulfoxide)IrCl5][dihexyl sulfoxide(+1H)]
• CAS: 924266-33-1
• 化学式: C₁₂H₂₆Cl₅IrOS*C₁₂H₂₇OS
• 分子量: 807.301
• InChiKey: HGDLPYMIOUXFFJ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸 、 potassium hexachloroiridate(IV) 、 二-n-己基亚砜 以 盐酸 为溶剂， 生成 [(dihexyl sulfoxide)IrCl5][dihexyl sulfoxide(+1H)]
  参考文献：
  名称：

  Extraction of iridium(IV) by dihexyl sulfoxide from hydrochloric acid solutions

  摘要：

  The extraction of iridium(IV) by dihexyl sulfoxide from hydrochloric acid solutions was studied. Optimum conditions for the extraction of iridium(IV) were determined. It was found that an ion-association mechanism of iridium(IV) extraction took place in the test extraction systems at a phase contact time of 10 min. As the phase contact time was increased, the extraction took place by a mixed mechanism. One extractant molecule was incorporated into the inner coordination sphere of the iridium(IV) ion. This decreased the charge of the extracted complex to unity.

  DOI：

  10.1134/s0036023606060209