4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I)) | 1392231-59-2

• 英文名称: 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I))
• 英文别名: [RhI(COD)]₂(μ-^DippTrz₂)
• CAS: 1392231-59-2
• 化学式: C₅₂H₆₈I₂N₆Rh₂
• 分子量: 1236.77
• InChiKey: WEBMDCZCNNWIJX-XTSSNGSKSA-L

反应信息

• 作为反应物：
  描述：

  一氧化碳 、 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I)) 以 乙腈 为溶剂， 反应 0.25h， 以78%的产率得到4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)dicarbonyliodidorhodium(I))
  参考文献：
  名称：

  Di-Mesoionic Carbene-Bridged Complexes of Rh₂, Ir₂, and RhIr: A Stepwise Metalation Strategy for the Synthesis of di-MIC-Bridged Mixed-Metal Systems

  摘要：

  A meta-substituted benzene-bridged ditriazolium salt has been prepared using copper-catalyzed azide-alkyne cycloaddition (CuAAC or "click" chemistry) and methylation protocols. Metalation of this dicationic species by basic-ligand-containing [Rh(mu-OMe)(COD)](2) and [Ir(mu-OMe)(COD)](2) precursors provides homobimetallic complexes of Rh and Jr bridged by a 1,2,3-triazol-5-ylidene-type di-mesoionic carbene (di-MIC) via an "internal-base" strategy. By using only 1/2 equiv of the internal-base precursor, mononuclear MIC-anchored/pendent-triazolium intermediates have been isolated, in which only one end of the ditriazolium salt has been deprotonated and attached to Rh or Jr. Reaction of these pendent intermediates with another 1/2 equiv of an internal-base precursor affords either the aforementioned homobimetallic products or an analogous di-MIC-bridged, mixed-metal Ir/Rh complex.

  DOI：

  10.1021/om300423z
• 作为产物：
  描述：

  methoxy(cyclooctadiene)rhodium(I) dimer 、 4,4′-(1,3-phenylene)bis(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium) trifluoromethanesulfonate 在 potassium iodide 作用下， 以 乙腈 为溶剂， 反应 1.0h， 以83%的产率得到4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I))
  参考文献：
  名称：

  Di-Mesoionic Carbene-Bridged Complexes of Rh₂, Ir₂, and RhIr: A Stepwise Metalation Strategy for the Synthesis of di-MIC-Bridged Mixed-Metal Systems

  摘要：

  A meta-substituted benzene-bridged ditriazolium salt has been prepared using copper-catalyzed azide-alkyne cycloaddition (CuAAC or "click" chemistry) and methylation protocols. Metalation of this dicationic species by basic-ligand-containing [Rh(mu-OMe)(COD)](2) and [Ir(mu-OMe)(COD)](2) precursors provides homobimetallic complexes of Rh and Jr bridged by a 1,2,3-triazol-5-ylidene-type di-mesoionic carbene (di-MIC) via an "internal-base" strategy. By using only 1/2 equiv of the internal-base precursor, mononuclear MIC-anchored/pendent-triazolium intermediates have been isolated, in which only one end of the ditriazolium salt has been deprotonated and attached to Rh or Jr. Reaction of these pendent intermediates with another 1/2 equiv of an internal-base precursor affords either the aforementioned homobimetallic products or an analogous di-MIC-bridged, mixed-metal Ir/Rh complex.

  DOI：

  10.1021/om300423z