2,5-diferrocenyl-1-(4-fluorophenyl)pyrrole | 1488428-05-2

• 英文名称: 2,5-diferrocenyl-1-(4-fluorophenyl)pyrrole
• CAS: 1488428-05-2
• 化学式: C₃₀H₂₄FFe₂N
• 分子量: 529.22
• InChiKey: VKJCCZHSXRDREJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4-bis(ferrocenyl)-1,3-butadiyne 、 4-氟苯胺 在 copper(l) chloride 作用下， 反应 24.0h， 以68%的产率得到2,5-diferrocenyl-1-(4-fluorophenyl)pyrrole
  参考文献：
  名称：

  Synthesis of 2,5-diferrocenyl five-membered heterocyclic compounds and their electrochemistry

  摘要：

  A series of 2,5-diferrocenyl substituted five-membered heterocyclic compounds, 2,5-diferrocenyl-1-phenylpyrrole (1), 2,5-diferrocenyl-1-(4-fluorophenyl)-pyrrole (2), 2,5-diferrocenyl-1-(4-ethoxyphenyl)-pyrrole (3), 2,5-diferrocenyl-1-(4-ethylphenyl)-pyrrole (4), 2,5-diferrocenylthiophene (5), and 2,5-diferrocenylfuran (6), were synthesized using one-pot cycloaddition of ferrocenyl alkyne and characterized by elemental analysis, FT-IR, MS, and NMR. The molecular structures of 1, 2, 5, and 6 were determined using single-crystal X-ray diffraction. Electronic communication between two ferrocenyl units of 1-6 was investigated using cyclic voltammetry. These compounds have two well-resolved electrochemically reversible one-electron-transfer processes using [NBu4][PF6] as the supporting electrolyte. The electrochemical studies reveal that electronic communication between two ferrocenyl units depend on the heteroatoms.

  DOI：

  10.1080/00958972.2013.841902