5-ferrocenyl-4-carbaldehyde-1,2,3-triselenole | 1415328-31-2

• 英文名称: 5-ferrocenyl-4-carbaldehyde-1,2,3-triselenole
• CAS: 1415328-31-2
• 化学式: C₁₃H₁₀FeOSe₃
• 分子量: 474.949
• InChiKey: FIUQIKJGPIDPOM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [(iron)3(carbonyl)9(μ3-Se)2] 、 [(iron)2(hexacarbonyl)(μ-SeC(ferrocenyl)C(CHO)Se)] 在 trimethylamine-N-oxide dihydrate 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 以81%的产率得到5-ferrocenyl-4-carbaldehyde-1,2,3-triselenole
  参考文献：
  名称：

  Synthesis, structure and redox property of first 1,2,3-triselenole

  摘要：

  Photolysis of [Fe3Se2(CO)(9)] with 3-ferrocenylpropynal in hexane yields an adduct of [Fe2Se2(CO)(6)] and FcC(2)CHO, [(CO)(6)Fe-2{mu-SeC(Fc)]=C(CHO)Se}] (1). Subsequent reaction of 1 with [Fe2Se2(CO)(6)] in presence of excess of Me3NO center dot 2H(2)O in THF leads to formation of a novel 5-ferrocenyl-4-carbaldehyde-1,2,3-triselenole (2). Its electrochemistry has been investigated by cyclic voltammetry, which shows two successive quasi-reversible oxidations. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.09.009