| 1133415-67-4

• CAS: 1133415-67-4
• 化学式: C₅₈H₄₆Cl₂N₂O₄P₂Pd₂
• 分子量: 1180.71
• InChiKey: OGOWKNJIELQYRO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 2,6-二甲基苯基异腈 以 二氯甲烷 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Conversion of novel palladacycles into oxopyrrolo[3,4-b]quinolines

  摘要：

  The quinolinylcyclopalladated complexes 3a-b were synthesised in good yields (81% and 77%) by the insertion reaction of the prepared dinuclear palladium complexes [Pd(C,N-2-C9H4N-CHO-3-R-6)Cl(PPh3)](2) [(R = H (2a), R = Me (2b)] with isonitrile XyNC (Xy = 2,6-Me2C6H3). The cyclopalladated complexes 3a-b were also obtained in low yields (39% and 33.5%) via a one pot oxidative addition reaction of quinoline chloride 1a-b with isonitrile XyNC:Pd(dba)(2) (4:1). The reactions of 3a-b with TI(TfO) (TfO=triflate, CF3SO3) in the presence of H2O or EtOH causes depalladation reactions of the complexes to provide the corresponding organic compounds 4a-b, 5a-b and 6a-b in yields (41%. 27% and 18-19%). The products were characterized by satisfactory elemental analyses and spectral studies (IR, H-1, C-13 and P-31 NMR). The crystal structures of 2a, 3a and 3b were determined by X-ray diffraction studies. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.054
• 作为产物：
  描述：

  三苯基膦 、 2-氯-6-甲氧基喹啉-3-甲醛 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 以 丙酮 为溶剂， 以31.2%的产率得到
  参考文献：
  名称：

  Conversion of novel palladacycles into oxopyrrolo[3,4-b]quinolines

  摘要：

  The quinolinylcyclopalladated complexes 3a-b were synthesised in good yields (81% and 77%) by the insertion reaction of the prepared dinuclear palladium complexes [Pd(C,N-2-C9H4N-CHO-3-R-6)Cl(PPh3)](2) [(R = H (2a), R = Me (2b)] with isonitrile XyNC (Xy = 2,6-Me2C6H3). The cyclopalladated complexes 3a-b were also obtained in low yields (39% and 33.5%) via a one pot oxidative addition reaction of quinoline chloride 1a-b with isonitrile XyNC:Pd(dba)(2) (4:1). The reactions of 3a-b with TI(TfO) (TfO=triflate, CF3SO3) in the presence of H2O or EtOH causes depalladation reactions of the complexes to provide the corresponding organic compounds 4a-b, 5a-b and 6a-b in yields (41%. 27% and 18-19%). The products were characterized by satisfactory elemental analyses and spectral studies (IR, H-1, C-13 and P-31 NMR). The crystal structures of 2a, 3a and 3b were determined by X-ray diffraction studies. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.054