[Ru(η⁵-indenyl)(η⁶-indene)](PF6) | 1401298-59-6

• 英文名称: [Ru(η⁵-indenyl)(η⁶-indene)](PF6)
• CAS: 1401298-59-6
• 化学式: C₁₈H₁₄Ru*F₆P
• 分子量: 476.343
• InChiKey: OVRVPQBBPJRIHU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 bis(η5-indenyl)ruthenium(II) 、 三氟乙酸 以 二氯甲烷 、 水 为溶剂， 以23%的产率得到[Ru(η⁵-indenyl)(η⁶-indene)](PF6)
  参考文献：
  名称：

  Synthesis of iron complexes [(η5-indenyl)FeL3]+ from the readily available[(η5-indenyl)Fe(η6-indene)]+

  摘要：

  The iron complex [(eta(5)-indenyl)Fe(eta(6)-indene)](+) (1) was prepared via one-pot procedure in 25% yield by reaction of FeCl3 with indenyl lithium giving Fe(eta(5)-indenyl)(2) and its subsequent protonation with CF3COOH. Cation 1 reacts with 2e ligands L (L = (BuNC)-Bu-t, P(OMe)(3), P(OEt)(3), PMe(OEt)(2)) under visible light irradiation giving the half-sandwich complexes [(eta(5)-indenyl)FeL3](+) in 50-80% yields. Protonation of the related ruthenium complex Ru(eta(5)-indenyl)(2) gives cation [(eta(5)-indenyl)Ru(eta(6)-indene)](+) (23% yield). The structures of [1]BF4 and [(eta(5)-indenyl)Fe((BuNC)-Bu-t)(3)]PF6 were determined by X-ray diffraction. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.06.018