| 906461-99-2

• CAS: 906461-99-2
• 化学式: C₁₈H₂₆FeN*F₆P
• 分子量: 457.222
• InChiKey: XKTLDGMNOPLEAL-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸 、 ammonium hexafluorophosphate 、 N-(hexyl)-2-aza[3]ferrocenophane 以 盐酸 、 丙酮 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  Structure and properties of protonated N-alkyl-2-aza[3]ferrocenophanes

  摘要：

  Protonation of N-alkyl-2-aza[3]ferrocenophanes by HCl and NH4PF6 affords hexafluorophosphate salts having a trialkylammonium group. Structures of the protonated and unprotonated N-(p-methylbezyl)-2-aza[3]ferrocenophanes were determined by X-ray crystallography. Variable temperature C-13{H-1} NMR spectra of the N-protonated N-hexyl-2-aza[3]ferrocenophane revealed inversion of the nitrogen of the 2-aza[3]ferrocenophane on the NMR time scale probably via partial deprotonation of the nitrogen atom. Cyclic voltammograms of the N-protonated compounds exhibited reversible redox peaks at higher potentials than those of the corresponding neutral ferrocenophanes. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.04.005