| 244629-93-4

• CAS: 244629-93-4
• 化学式: C₁₁H₈MnO₄
• 分子量: 259.12
• InChiKey: AFTWTEWEGPMHMO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  乙烯双(三苯基磷)铂 、 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Activation of a Carbon-Oxygen Bond of Benzofuran by Precoordination of Manganese to the Carbocyclic Ring: A Model for Hydrodeoxygenation

  摘要：

  Stable unsaturated heterocycles such as benzofuran are difficult to remove from petroleum by conventional catalytic hydrotreating. However, in a model system, coordination of Mn(CO)(3)(+) to the aromatic ring of benzofuran activates the C-O bond towards insertion of [Pt(PPh(3))(2)] [Eq. (1)]. The insertion is preceded by precoordination to the furan C=C bond; thus, the 2,3-dihydro analogue of 1, which lacks this double bond, does not undergo insertion of the Pt moiety.

  DOI：

  10.1002/(sici)1521-3773(19990802)38:15<2206::aid-anie2206>3.0.co;2-l