cis-dichloro-(N-Di-isopropylphosphino-N,N',N''-trimethylethylenediamine, P,N)platinum(II) | 389604-07-3

• 英文名称: cis-dichloro-(N-Di-isopropylphosphino-N,N',N''-trimethylethylenediamine, P,N)platinum(II)
• CAS: 389604-07-3
• 化学式: C₁₁H₂₇Cl₂N₂PPt
• 分子量: 484.309
• InChiKey: IHSYSMRSAHZIAO-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 diisopropylphosphino-N,N',N''-trimethylethylenediamine 以 二氯甲烷 为溶剂， 生成 cis-dichloro-(N-Di-isopropylphosphino-N,N',N''-trimethylethylenediamine, P,N)platinum(II)
  参考文献：
  名称：

  Platinum complexes of tertiary amine functionalised phosphines

  摘要：

  The reaction of several tertiary amine functionalised phosphines with [Pt(COD)Cl-2] has been studied. Reactions with ratios of L:Pt = 2 proceeded cleanly to give either cis or trans complexes depending on the cone angle of the phosphines. The trans complexes could also be prepared by reaction with Zeise's salt. Reactions of [Pt(COD)Cl-2] with L:Pt = 1 are less straightforward, and a mixture of cis and trans monodentate complexes, and in one example, a chelate complex have been isolated. The X-ray crystal structures of [PtCl2(eta(2)-(Pr2PN)-Pr-i(Me)CH2CH2NMe2)] and a monodentate complex [trans-PtCl2(eta(1)-(Pr2PNH)-Pr-i-c-NC5H10)(2)] are reported. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01329-3