| 147858-65-9

• CAS: 147858-65-9；147858-63-7；147858-66-0
• 化学式: C₁₈H₂₃CrNO₂S
• 分子量: 369.448
• InChiKey: GLQVMSQOLRNJCL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三羰基-1,3,5-三甲基苯铬 、 2-(t-butylthio)acrylonitrile 以 甲苯 为溶剂， 生成 、 、
  参考文献：
  名称：

  Umsetzungen von metallorganylen mit dem capto-dativ substituierten ethylen H2CC(CN)(StButyl)

  摘要：

  The olefin H2C=C(CNXS(t)Bu) (A) has one donor- and one acceptor substituent in a geminal position. Because such a compound is expected to undergo multiple reactions, A was reacted with some organometallic substrates. The reaction of A with [CpFe(CO)2]2 leads to the sulphur bridged cluster (CP)2 Fe2[mu2,eta2-S=C(CN)CH2(CH3)C=S] (1). With (Mes)Cr(CO)2(THF) A reacts at 0-degrees-C to give the three isomeric compounds (Mes)Cr(CO)2[eta2-H2C=C(CNXS(t)Butyl)] (2), (Mes)Cr(CO)2[S((t)Bu)C(CN)=CH2] 2a and (MeS)Cr(CO)2[NC-C(S(t)Bu)=CH2] (2b). By thermolysis of (C5Me5)2Co2(mu-CO)2 or CpRh(CO)2 with A the complexes (C5Me5)Co(CO)[eta2-S=C(CN)(CH2-(t)Butyl) (3) and CP2Rh2[mu2, eta1, eta2-CH=C(CN)](mu2-S(t)Butyl) (4) were obtained. All newly synthesized compounds have been analysed and characterised by the usual spectroscopic methods. X-ray diffraction studies have been done of compounds 1-4.

  DOI：

  10.1016/0022-328x(93)83062-z