[Ti(η(5)-C5Me5)(PhCCCH2O-κO)3] | 665031-58-3

• 英文名称: [Ti(η(5)-C5Me5)(PhCCCH2O-κO)3]
• CAS: 665031-58-3
• 化学式: C₃₇H₃₆O₃Ti
• 分子量: 576.571
• InChiKey: WJGUTQLXHLTJRT-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (η(3):η(4)-1,2,3-trimethyl-4,5-dimethylenecyclopentenyl)(η(5)-pentamethylcyclopentadienyl)titanium 、 3-苯基-2-丙炔-1-醇 以 甲苯 为溶剂， 生成 [Ti(η(5)-C5Me5)(PhCCCH2O-κO)3]
  参考文献：
  名称：

  The synthesis of (η5-cyclopentadienyl)titanium(IV) alkoxides by alcoholysis of the Ti–π-ligand bond in permethyl η3:η4-allyldiene-(η5-cyclopentadienyl)titanium(II)

  摘要：

  The eta(3):eta(4)-allyldiene-(eta(5)-cyclopentadienyl)titanium(II) complex [Ti(eta(5)-C5Me5){eta(3):eta(4)-C5Me3(CH2)(2)}] (1) reacts with three molar equivalents of substituted propargylic alcohols FcCequivalent toCCMe(2)(OH) (2a) and PhCequivalent toCCH(2)OH (2b) at elevated temperature to give (eta(5)-pentamethylcyclopentadienyl)titanium(IV) alkoxides [Ti(eta(5) -C5Me5)(FcCequivalent toCCMe(2)O-kappaO)(3)] (3a) and [Ti(eta(5)-C5Me5) (PhCequivalent toCCH(2)O-kappaO)(3)] (3b), respectively. The crystal structure of 3a has been determined by single-crystal X-ray diffraction. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00151-5