| 91594-50-2

• CAS: 91594-50-2
• 化学式: C₂₈H₂₇FeO₂P
• 分子量: 482.342
• InChiKey: ICTPLDUEAHYNHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  溴甲苯 、 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Stereoselective carbon–carbon bond formation via alkylation of [(η-⁵C₅H₅)Fe(PPh₃)(CO)(COMeCHR)](R = Me,Prⁿ,Ph): X-ray crystal structure of (Z)-[(η⁵-C₅H₅)Fe(PPh₃)(CO)(COMeCHMe)]

  摘要：

  [(η-2C5H5)Fe(PPh3)(CO)(Mthoxycarbene)]+ complexes, prepared either from terminal acetylenes or from the corresponding acyl complexes, are stereoselectively deprotonated, as evidenced by the crystal structure of (Z)-[(η5-C5H5)Fe(PPh3)(CO)(COMeCHMe)], to (Z)-methoxyvinyl complexes which can be stereoselectively alkylated under mild conditions to give elaborated acyl complexes.

  DOI：

  10.1039/c39840000745
• 作为产物：
  描述：

  在 KOBut 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Stereoselective carbon–carbon bond formation via alkylation of [(η-⁵C₅H₅)Fe(PPh₃)(CO)(COMeCHR)](R = Me,Prⁿ,Ph): X-ray crystal structure of (Z)-[(η⁵-C₅H₅)Fe(PPh₃)(CO)(COMeCHMe)]

  摘要：

  [(η-2C5H5)Fe(PPh3)(CO)(Mthoxycarbene)]+ complexes, prepared either from terminal acetylenes or from the corresponding acyl complexes, are stereoselectively deprotonated, as evidenced by the crystal structure of (Z)-[(η5-C5H5)Fe(PPh3)(CO)(COMeCHMe)], to (Z)-methoxyvinyl complexes which can be stereoselectively alkylated under mild conditions to give elaborated acyl complexes.

  DOI：

  10.1039/c39840000745

文献信息

• Baird, Gordon J.; Davies, Stephen G.; Maberly, Timothy R., Organometallics, 1984, vol. 3, # 11, p. 1764 - 1765
  作者：Baird, Gordon J.、Davies, Stephen G.、Maberly, Timothy R.

  DOI：——

  日期：——