| 143053-92-3

• CAS: 143053-92-3
• 化学式: C₅₄H₄₁PRuS₂
• 分子量: 886.095
• InChiKey: SKQDJMNQLJEGOG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 CO 作用下， 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  A monomeric ruthenium thiolato complex with a chelated η6-arene ligand. The preparation and structure of [Ru{2-(η6-Ph)-6-PhC6H3S}(2,6-Ph2C6H3S)(PPh3)]

  摘要：

  Reaction of [RuCl2(PPh3)3] with the 2,6-diphenylthiophenolate anion (DPT) gives the complex [Ru(eta-6-DPT)(DPT)(PPh3)], with one thiol phenyl substituent eta-6-bonded to the ruthenium. The X-ray crystal structure reveals a distorted piano stool type of geometry. Crystal data: space group P2(1)/c, a = 14.204(4), b = 9.503(5), c = 31.680(9) angstrom, beta = 97.40(3)-degrees, Z = 4. The eta-6-arene ligand is labile and can readily be replaced by CO and 1,2-bis(diphenylphosphino)ethane.

  DOI：

  10.1016/s0020-1693(00)85829-6
• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 2,6-diphenylthiophenol 在 triethylamine 作用下， 以 甲醇 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  A monomeric ruthenium thiolato complex with a chelated η6-arene ligand. The preparation and structure of [Ru{2-(η6-Ph)-6-PhC6H3S}(2,6-Ph2C6H3S)(PPh3)]

  摘要：

  Reaction of [RuCl2(PPh3)3] with the 2,6-diphenylthiophenolate anion (DPT) gives the complex [Ru(eta-6-DPT)(DPT)(PPh3)], with one thiol phenyl substituent eta-6-bonded to the ruthenium. The X-ray crystal structure reveals a distorted piano stool type of geometry. Crystal data: space group P2(1)/c, a = 14.204(4), b = 9.503(5), c = 31.680(9) angstrom, beta = 97.40(3)-degrees, Z = 4. The eta-6-arene ligand is labile and can readily be replaced by CO and 1,2-bis(diphenylphosphino)ethane.

  DOI：

  10.1016/s0020-1693(00)85829-6