[Pd(4-(COH)C6H3C(H)=NCy-C2,N)(Ph2PCH2CH2CH2N(=CMe2)-P,N)][PF6] | 523977-79-9

• 英文名称: [Pd(4-(COH)C6H3C(H)=NCy-C2,N)(Ph2PCH2CH2CH2N(=CMe2)-P,N)][PF6]
• CAS: 523977-79-9
• 化学式: C₃₂H₃₈N₂OPPd*F₆P
• 分子量: 749.024
• InChiKey: KTVLPSXYCLXOBC-GWTRRZIHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 N-(3-diphenylphosphanylpropyl)propan-2-imine 、 [Pd(5-(COH)C6H3C(H)N(cyclohexyl)-C2,N)(μ-Cl)]2 以 丙酮 为溶剂， 以62%的产率得到[Pd(4-(COH)C6H3C(H)=NCy-C2,N)(Ph2PCH2CH2CH2N(=CMe2)-P,N)][PF6]
  参考文献：
  名称：

  Cyclometallated complexes of Pd(II) with heterobidentate P, As and P, N coordinating ligands

  摘要：

  Treatment of the choride-bridged dimer [Pd{4-(COH)C6H3C(H)=N(Cy)-C2,N}(mu-Cl)](2) (1), with Ph2PCH2CH2AsPh2 (arphos) in 1:1 molar ratio in acetone gave the dinuclear complex [{Pd[4-(COH)C6H3C(H)=N(Cy)-C2,N](Cl)}(2)(mu-Ph2PCH2CH2AsPh2)] (2), with the arsinophosphine as a bridging ligand, and in 1:2 molar ratio in the presence of NH4PF6 gave the mononuclear compound [Pd{4-(COH)C6H3C(H)=N(Cy)-C2,N}(Ph2PCH2CH2AsPh2-P,As)][PF6], (3), with the arsinophosphine chelated to the metal center. Reaction of 1 with Ph2PCH2CH2CH2NH2 in 1:2 molar ratio in acetone and NH4PF6 afforded [Pd{4-(COH)C6H3C(H)= N(Cy)-C2,N}{Ph2PCH2CH2CH2N(=CMe2)-P,N}[PF6](4), after intermolecular condensation between the aminophosphine and the solvent. Condensation was precluded by treatment in toluene to give the mononuclear compound [Pd{4-(COH)C6H3C(H)= N(Cy)-C2,N}(Ph2PCH2CH2CH2NH2-P,N)][PF6], (5).H-1 P-31{H-1} and C-13{H-1}-NMR, IR and mass spectral data are given. The crystal structures of compounds 2-4 have been determined by X-Ray crystallography. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02066-1