| 681293-87-8

• CAS: 681293-87-8
• 化学式: C₂₈H₄₁O₂Ru₃*F₆P*H₂O
• 分子量: 875.822
• InChiKey: LRGFSEAFOYCSKC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 以 正己烷 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and molecular structure of the trinuclear ruthenium cluster cations [H3Ru3(C6H6)(C6H2Me4)2(O)]+ and [H3Ru3{C6H5(CH2)2OH}(C6H2Me4)2(O)]+

  摘要：

  The trinuclear arene-ruthenium cluster cations [H3Ru3(C6H6)(C6H2Me4)(2)(O)](+) (2) and [H3Ru3{C6H5(CH2)(2)OH}(C6H2Me4)(2)(O)](+) (3) have been synthesised from the dinuclear precursor [H3Ru2(C6H2Me4)(2)](+) (1) and the mononuclear complexes [Ru(C6H6)(H2O)(3)](2+) and [Ru{C6H5(CH2)(2)OH}(H2O)(3)](2+), isolated and characterised as the tetrafluoroborate salts. Cations 2 and 3 are analogues of the cluster cation [H3Ru3(C6H6)(C6Me6)(2)(O)](+) which was found to catalyse the hydrogenation of benzene to give cyclohexane under biphasic conditions (supramolecular cluster catalysis'). The single-crystal X-ray structure analyses of 2 and 3 have been determined. Unlike [2][BF4](.)3H(2)O, [3][PF6](H2O)-H-. shows a dimeric structure in the solid state, thanks to hydrogen bonds between the hydroxo function of one molecule of 3, a water molecule and the oxo cap of an other molecule of 3. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00383-9