bis(N-(9-anthracenyl)-4'-(4-pyridyl)urea)(acetato)bromozinc(II) monohydrate | 1239037-74-1

• 英文名称: bis(N-(9-anthracenyl)-4'-(4-pyridyl)urea)(acetato)bromozinc(II) monohydrate
• CAS: 1239037-74-1
• 化学式: C₄₂H₃₃BrN₆O₄Zn*H₂O
• 分子量: 849.071
• InChiKey: VZFFHWDREFKPCE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-(9-anthracenyl)-N'-(4-pyridyl)-urea 、 四丁基溴化铵 、 zinc(II) acetate dihydrate 以 甲醇 为溶剂， 生成 bis(N-(9-anthracenyl)-4'-(4-pyridyl)urea)(acetato)bromozinc(II) monohydrate
  参考文献：
  名称：

  Three hydrogen-bonded nanotubular zinc(II) complexes of N-(9-anthracenyl)-N′-(4-pyridyl)-urea

  摘要：

  Three hydrogen-bonded nanotubular zinc(II) complexes of a monodentate ligand N-(9-anthracenyl)-N'-(4-pyridyl)urea (L), [Zn(OAc)(2)L-2]center dot H2O (1), [ZnBr(OAc)L-2]center dot H2O (2) and [ZnCl(OAc)L-2]center dot 4H(2)O (3). were synthesized and structurally characterized. In the complexes, the central metal ion is tetrahedrally coordinated by the pyridyl nitrogen atoms of two ligands and different anions, while the urea groups of the ligands self-associate into the typical urea tape through R-2(1)(6) hydrogen bonds, which are essential for the formation of the nanotubes. The fluorescence properties of ligand L and the complexes were studied in the solid state at room temperature. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.04.018