| 208184-20-7

• CAS: 208184-20-7
• 化学式: C₃₆H₈₁KO₁₂Si₃Sn
• 分子量: 948.097
• InChiKey: NZEIUQJFEUAGFG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [K{OSi(OtBu)₃}] 、 tin(ll) chloride 以 四氢呋喃 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Alkoxy(siloxy) complexes of tin, lead and bismuth

  摘要：

  By reaction of PbCl2 with 3 equivalents of NaOSi((OBu)-Bu-t)(3), the ate complex NaPb[OSi((OBu)-Bu-t)(3)](3) was obtained. This compound possesses a structure containing a 3-coordinate, trigonal prismatic lead center, and a 6-coordinate Na atom encapsulated in an oxygen matrix formed by the bridging siloxy and tert-butoxy groups of the -OSi((OBu)-Bu-t)(3) ligands. The neutral lead complex Pb[OSi((OBu)-Bu-t)(3)](2) .(BuOH)-Bu-t . CH3CN was obtained from reaction of Pb-3(mu-(OBu)-Bu-t)(6) with HOSi((OBu)-Bu-t)(3). The tin complex KSn[OSi((OBu)-Bu-t)(3)](3), prepared from SnCl2 and KOSi((OBu)-Bu-t)(3), is isomorphous with NaPb[OSi((OBu)-Bu-t)(3)](3). The bismuth compounds Bi[OSi((OBu)-Bu-t)(3)](3) and Bi[OSi((OBu)-Bu-t)(2)Ph](3) were obtained by similar methods. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00260-x