Synthesis and characterization of [PPh4][M(diod)2], MNi, Pd, Cu or Au; crystal structure of [PPh4][Cu(diod)2]
摘要:
The complexes [P(C6H5)(4)][M(diod)(2)][where M = Ni, Pd, Cu or Au (2a, b, c, d)] have been prepared and characterized spectroscopically, electrochemically and by X-ray structure determination for 2c. Preparation of 2d involved isolation of an intermediate complex with only one died ligand. The Ni complex 2a forms semiconducting charge transfer complexes with TTF and BEDT-TTF. Copyright (C) 1997 Elsevier Science Ltd.
Synthesis and characterization of [PPh4][M(diod)2], MNi, Pd, Cu or Au; crystal structure of [PPh4][Cu(diod)2]
摘要:
The complexes [P(C6H5)(4)][M(diod)(2)][where M = Ni, Pd, Cu or Au (2a, b, c, d)] have been prepared and characterized spectroscopically, electrochemically and by X-ray structure determination for 2c. Preparation of 2d involved isolation of an intermediate complex with only one died ligand. The Ni complex 2a forms semiconducting charge transfer complexes with TTF and BEDT-TTF. Copyright (C) 1997 Elsevier Science Ltd.