| 470475-24-2

• CAS: 470475-24-2
• 化学式: C₁₄H₂₃ClN₂Ru
• 分子量: 361.825
• InChiKey: AHWAVRRJCCDQSX-VORQKQJQSA-M

反应信息

• 作为产物：
  描述：

  Ru(η6-C6H6)(η-(C3H7N)2CCH3)Cl 、 氘代苯 以 1,2-二氯乙烷 为溶剂， 生成
  参考文献：
  名称：

  Access to Novel Ruthenium−Amidinate Complexes, (η⁶-arene)Ru(η²-amidinate)X and [Ru(η²-amidinate)(MeCN)₄]⁺PF₆^- by Photochemical Displacement of the Benzene Ligand in (η⁶-C₆H₆)Ru(η²-amidinate)X

  摘要：

  Novel ruthenium-amidinate complexes, (eta(6)-C6H5R)Ru(eta(2)-amidinate)X (R = Me, OMe, F) (4) and [Ru(eta(2)-amidinate)(MeCN)(4)]+PF6- (5) are synthesized by photochemical displacement of the benzene ligand in (eta(6)-C6H6)Ru(eta(2)-amidinate)X (3) by arenes or MeCN. The acetonitrile ligands of 5 are easily replaceable by other a-donor ligands (L) such as pyridines, phosphines, and isocyanides to afford the corresponding derivatives, [Ru(eta(2)-amidinate)(MeCN)(n)(L)(4-n)(+)] PF6- (n = 1 or 2).

  DOI：

  10.1021/om020227y