[Ru(N,N,N''-trimethyl-1,4,7-triazacyclononane)(1,2,5,6-η-cycloocta-1,5-diene)H]ClO4 | 161697-56-9

• 英文名称: [Ru(N,N,N''-trimethyl-1,4,7-triazacyclononane)(1,2,5,6-η-cycloocta-1,5-diene)H]ClO4
• CAS: 161697-56-9
• 化学式: C₁₇H₃₄N₃Ru*ClO₄
• 分子量: 480.998
• InChiKey: GZDVEEHTJZCIDO-KJWGIZLLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(1,5-cyclooctadiene)ruthenium(II) 、 sodium perchlorate 、 1,4,7-三甲基-1,4,7-三氮杂环壬烷 、 锌 以 乙醇 、 水 为溶剂， 以12%的产率得到[Ru(N,N,N''-trimethyl-1,4,7-triazacyclononane)(1,2,5,6-η-cycloocta-1,5-diene)H]ClO4
  参考文献：
  名称：

  Preparation and crystal structures of cationic dienehydrido and dienyl ruthenium complexes containing N,N′,N″-trimethyl-1,4,7-triazacyclononane

  摘要：

  The reaction between [{Ru(cod)Cl-2}(n)] (cod = cycloocta-1,5-diene) and N,N',N''-trimethyl-1,4,7-triazacyclononane (tacn) in ethanol-water gave [Ru(tacn)(1,2,5,6-eta-cod)H]ClO4 1. When tert-butyl alcohol was used as the solvent, [Ru(tacn)(1,2,3,4,5-eta-C8H11)]ClO4 2 was obtained. The Ru-H moiety in 1 is characterized by a H-1 NMR signal at delta -6.11 and a nu(Ru-H) stretch at 2040 cm(-1). Crystal structure analysis shows that the co-ordinated cod of 1 is in the tub form, whereas complex 2 has an eta(5)-cyclooctadienyl ligand.

  DOI：

  10.1039/dt9950000227