| 415707-40-3

• CAS: 415707-40-3
• 化学式: C₂₄H₄₅P₂Pt
• 分子量: 590.649
• InChiKey: QZBRQOBZFPAEPT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氢气 、 (2,6-bis[(di-t-butylphosphino)methyl]phenyl)hydridoplatinum 生成
  参考文献：
  名称：

  Palladium complexes with PCP ligands.

  摘要：

  Abstraction of chloride from the Pd complex {[eta(3)-2,6-((Bu2PCH2)-Bu-1)(2)C6H3)]PdCl with AgBF4 in THF gives {[eta(3)-2,6-((Bu2PCH2)-Bu-1)(2)C6H3)]Pd(THF)}+BF4-. Attemped crystallization of this THF complex produced the aqua complex {[eta(3)-2,6-((Bu2PCH2)-Bu-1)(2)C6H3)]Pd(OH2))+BF4-. Crystal structures of two crystalline forms of this compound are reported. In In {[eta(3)-2,6-((Bu2PCH2)-Bu-1)(2)C6H3)]Pd(OH2)}(+) BF4- THF, one hydrogen of the water is hydrogen bonded to the oxygen of the THF, and the other hydrogen is hydrogen bonded to an F of the BF4- anion. Another crystalline form has no THF, but has both of the hydrogens of water hydrogen bonded to different BF4- anions, such that two different BF4- anions bridge two {[eta(3)-2,6-((Bu2PCH)-Bu-1)(2)C6H3)]Pd(OH2)}(+) cations. A crystal structure is also reported for the palladium chloride complex [eta(3)-2,6((Bu2PCH2)-Bu-1)(2)C6H3)]PdCl. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00736-8