| 638222-78-3

• CAS: 638222-78-3
• 化学式: C₂₁H₂₃FeNOSi
• 分子量: 389.352
• InChiKey: OKICIUBMLOKOEB-SQKCAUCHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  苯甲酰基二茂铁 、 三甲基氰硅烷 在 zinc(II) iodide 作用下， 以 二氯甲烷 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Synthesis of cyanohydrin trimethylsilyl ethers of acylferrocenes

  摘要：

  The addition of trimethylsilyl cyanide to acylferrocenes FcCOR (R. = Me, Et, Pr-n, Pr-i, Ph, p-MeOC6H4, o-ClC6H4, m-ClC6H4, p-ClC6H4, Fc; Fc = C5H4FeC5H5) catalyzed by zinc iodide in methylene chloride provided the corresponding cyanohydrin trimethylsilyl ethers in moderate to high yields. Factors affecting the reaction and yields of adducts were investigated. All new compounds were characterized by IR and H-1 NMR spectroscopies. In addition, the adducts of p-chlorobenzoylferrocene and diferrocenyl ketone were structurally determined by X-ray crystallography. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00262-6