cobalt(II) 2,9,16,23-tetracarboxylic acid phthalocyanine | 76096-57-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: cobalt(II) 2,9,16,23-tetracarboxylic acid phthalocyanine
• 英文别名: cobalt tetra-3-carboxyphthalocyanine；Co(3-COOH)4Pc；cobalt(2+);2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene-5,14,23,32-tetracarboxylic acid
• CAS: 76096-57-6
• 化学式: C₃₆H₁₆CoN₈O₈
• 分子量: 747.565
• InChiKey: FREHKJYWHDOTIE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  氯化亚砜 、 cobalt(II) 2,9,16,23-tetracarboxylic acid phthalocyanine 在 pyridine 作用下， 以 苯 为溶剂， 生成 cobalt(II) 2,9,16,23-tetracarboxylic acidchloride phthalocyanine
  参考文献：
  名称：

  Self-assembled monolayers (SAMs) of cobalt tetracarboxylic acidchloride phthalocyanine covalently attached onto a preformed mercaptoethanol SAM: A novel method

  摘要：

  A feasible method of fabricating phthalocyanine sensor was developed by covalent attachment of cobalt tetracarboxylic acidchloride phthalocyanine (CoTCACIPc) onto a preformed 2-mercaptoethanol (2-ME) self-assembled monolayer (SAM) modified gold electrode (designated as CoTCACfPc-2-ME-SAM). The surface concentration of the CoTCACIPc was found to be 4.58 x 10(-10) mol/cm(2). The sensor gave a linear response to L-cysteine over the concentration range 0.28-20 mu M with a detection limit of 5 x 10(-7) M and best response time of 2 s. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2005.10.004

文献信息

• Carboxy-substituted Phthalocyanine Metal Complexes
  作者：G. P. Shaposhnikov、V. E. Maizlish、V. P. Kulinich

  DOI：10.1007/s11176-005-0450-4

  日期：2005.9

  Metal complexes of carboxy-substituted phthalocyanines differing in the number of carboxy groups and their positions and those having carboxy groups together with other substituents were synthesized, and their spectral and some other properties were studied.

  合成了不同数量和位置的羧基取代酞菁金属配合物，以及同时具有羧基和其他取代基的化合物，并对它们的光谱及其他一些性质进行了研究。
• Lebedeva; Pavlycheva; V'yugin, Russian Journal of Inorganic Chemistry, 2004, vol. 49, # 2, p. 289 - 293
  作者：Lebedeva、Pavlycheva、V'yugin、Maizlish、Shaposhnikov

  DOI：——

  日期：——