[Ag(1,6-bis(4'-pyridyl)-2,5-diazahexane)]BF4*CH3CN | 300664-25-9

• 英文名称: [Ag(1,6-bis(4'-pyridyl)-2,5-diazahexane)]BF4*CH3CN
• 英文别名: [Ag(BPDH)]BF4*CH3CN
• CAS: 300664-25-9
• 化学式: Ag*BF₄*C₂H₃N*C₁₄H₁₈N₄
• 分子量: 478.049
• InChiKey: JJLBNGUHLQTYGM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四(乙酰腈)银(I)四氟硼酸 、 N,N′‐bis(pyridin‐4‐ylmethyl)ethane‐1,2‐diamine 、 乙腈 以 乙腈 为溶剂， 以54%的产率得到[Ag(1,6-bis(4'-pyridyl)-2,5-diazahexane)]BF4*CH3CN
  参考文献：
  名称：

  The synthesis, crystal structure and spectroscopic properties of a new two-dimensional silver(I) coordination network

  摘要：

  A flexible tetradentate ligand 1,6-bis(4'-pyridyl)-2,5-diazahexane (BPDH) reacts with tetrakis(acetonitrile)silver(I) tetrafluoroborate to form a novel two-dimensional network complex [Ag(BPDH)]BF(4). CH(3)CN. The compound crystallizes in monoclinic, space group P2(1)/n with a = 14.121(2), b = 7.0410(10), c = 19.803(3) Angstrom, beta = 94.700(10)degrees, V = 1962.3(5) Angstrom(3) and Z = 4. The solvate acetonitrile molecule and counter anions are incorporated in the channels formed between two adjacent sheets through C-H ... F, N-H ... F and N-H ... N hydrogen bonds. The spectroscopic properties of the complex as luminescent, thermogravimetric and electrospray mass spectrometry were also described. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00143-2