| 1442524-27-7

• CAS: 1442524-27-7
• 化学式: C₂₂H₂₇ClN₂O₂Rh
• 分子量: 489.827
• InChiKey: PJULFRUGKOUFEK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 2,2'-联吡啶-4,4'-二甲醇 以 甲醇 为溶剂， 反应 3.0h， 以92%的产率得到
  参考文献：
  名称：

  Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH

  摘要：

  A Rh(III) complex having a functionalized bpy-OH ligand that is potentially linkable to electrode surfaces was synthesized and fully characterized. The hydrido complex, which could be generated either electrochemically by cathodic reduction of the [eta(5)-Cp*Rh(bpy-OH)ClICI complex at 771 mV (versus Ag/AgCI) or chemically with formate, transformed NAD(+) efficiently into NADH with a TOF = 710 at 60 degrees C. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.04.011
• 作为试剂：
  描述：

  nicotinamide adenine dinucleotide 在 、 sodium formate 作用下， 以 aq. phosphate buffer 为溶剂， 反应 0.5h， 生成 还原型辅酶Ⅰ
  参考文献：
  名称：

  Functionalized bipyridyl rhodium complex capable of electrode attachment for regeneration of NADH

  摘要：

  A Rh(III) complex having a functionalized bpy-OH ligand that is potentially linkable to electrode surfaces was synthesized and fully characterized. The hydrido complex, which could be generated either electrochemically by cathodic reduction of the [eta(5)-Cp*Rh(bpy-OH)ClICI complex at 771 mV (versus Ag/AgCI) or chemically with formate, transformed NAD(+) efficiently into NADH with a TOF = 710 at 60 degrees C. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.04.011