[Ru(η5-C9H7)(1,3,5-triaza-7-phosphaadamantane)3]Cl | 1020731-33-2

• 英文名称: [Ru(η5-C9H7)(1,3,5-triaza-7-phosphaadamantane)3]Cl
• CAS: 1020731-33-2
• 化学式: C₂₇H₄₃N₉P₃Ru*Cl
• 分子量: 723.143
• InChiKey: OYZQISONCXOOGO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η5-indenyl)ruthenium(bis(triphenylphosphine))chloride 、 1,3,5-三氮杂-7-磷杂金刚烷 以 甲苯 为溶剂， 以53%的产率得到[Ru(η5-C9H7)(1,3,5-triaza-7-phosphaadamantane)3]Cl
  参考文献：
  名称：

  Novel hydridotris(pyrazolyl)borate ruthenium(II) complexes containing the water-soluble phosphane 1,3,5-triaza-7-phosphaadamantane: Synthesis and evaluation of DNA binding properties

  摘要：

  A series of half-sandwich ruthenium(H) complexes containing kappa(3) (N,N,N)-hydridotris(pyrazolyl)borate (kappa(3)(NNN)-Tp) and the water-soluble phosphane 1,3,5-triaza-7-phosphaadamantane (PTA) [RuX[kappa(3)(N,N,N)-Tp)(PPh3)(2-n)(PTA)(n)] (n = 2, X = Cl (1), n = 1, X = Cl (2), I (3), NCS (4), H (5)) and [Ru{kappa(3)(N,N,N)-Tp}(PPh3)(PTA)L][PF6] (L = NCMc (6), PTA (7)) have been synthesized. Complexes containing 1-methyl-3,5-diaza-1-azonia-7-phosphaadamantane(m-PTA) triflate [RuCl{kappa(3)(N,N,N)-Tp}(m-PTA)(2)][CF3SO3](2) (8) and [RuX{kappa(3)(N,N,N)-Tp) (PPh3)(m-PTA)][CF3SO3] (X = Cl (9), H (10)) have been obtained by treatment, respectively, of complexes 1, 2 and 5 with methyl triflate. Single crystal X-ray diffraction analysis for complexes 1, 2 and 4 have been carried out. DNA binding properties by using a mobility shift assay and antimicrobial activity of selected complexes have been evaluated. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.12.013